Morpholinium?Modified, Polyketone?Based Anion Exchange Membranes for Water Electrolysis
نویسندگان
چکیده
Water electrolysis is by far the most appealing method to produce green hydrogen. Among possible technologies, Anion Exchange Membrane (AEM) water electrolyzers are promising in medium term, as they make it avoid critical and noble materials catalyst components. However, AEMs still lacking performance stability, which has become current research focus. Here, we report facile inexpensive chemical modification of polyketone (PK) with a functional unit encompassing morpholinium positively charged group, fabrication self-standing membranes. The synthesis products investigated an ensemble physico-chemical spectroscopic techniques, including solid-state time-domain NMR, FT-IR, thermal analysis. membranes show good Ion Capacity values range 1.48–2.24 mmol g?1. A preliminary test shows that PK-based membrane comparable commercial one.
منابع مشابه
Polymer Electrolyte Membranes for Water Photo-Electrolysis
Water-fed photo-electrolysis cells equipped with perfluorosulfonic acid (Nafion® 115) and quaternary ammonium-based (Fumatech® FAA3) ion exchange membranes as separator for hydrogen and oxygen evolution reactions were investigated. Protonic or anionic ionomer dispersions were deposited on the electrodes to extend the interface with the electrolyte. The photo-anode consisted of a large band-gap ...
متن کاملPolysulfone-based Anion Exchange Membranes for Potential Application in Solid Alkaline Fuel Cells
In present research work, anion exchange membranes based on quaternized polysulfone with ammonium cation moieties (QAPSF) were prepared by chloromethylation, amination and alkalization. The chloromethylated polysulfone were characterized by 1HNMR spectroscopy and functionalization degree was determined according to peak area integration. Ion transport properties (ionic conductivity, ion exchang...
متن کاملElectrodialysis Heterogeneous Anion Exchange Membranes Filled with TiO2 Nanoparticles: Membranes' Fabrication and Characterization
In the current research, polyvinylchloride based mixed matrix heterogeneous anion exchange membranes were prepared by a solution casting technique. Titanium dioxide nanoparticles were also utilized as inorganic filler additive in the membrane fabrication. The effect of TiO2 nanoparticles concentration in the casting solution on the membrane physico-chemical properties was studied. Membrane wate...
متن کاملAnion Exchangers for Water Treatment: Ion Exchange
ation sciences is the puriRcation and recovery of solvents especially from HPLC and GPC usage. There is a range of equipment supplied for recycling of solvents and useful sources of information can be found on the internet, for example the web pages for B/R Instruments and Recycling Sciences are included in the Further Reading. The applications of distillation in analysis are widespread, with t...
متن کاملDesign of Anion Exchange Membranes and Electrodialysis Studies for Water Desalination
Anion exchange membranes are highly versatile and nowadays have many applications, ranging from water treatment to sensing materials. The preparation of anion exchange membranes (AEMs) from brominated poly(2,6-dimethyl-1,6-phenylene oxide) (BPPO) and methyl(diphenyl)phosphine (MDPP) for electrodialysis was performed. The physiochemical properties and electrochemical performance of fabricated me...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: ChemElectroChem
سال: 2023
ISSN: ['2196-0216']
DOI: https://doi.org/10.1002/celc.202201077